The chibi's super cute!
As for the face, you really could use some help on the hair, but I've seen you do much better so I won't tell you. Now, here's how you do side-view:
Start with doing a rough outline. It should look something like this: http://static.tvtropes.org/pmwiki/pub/images/ppd-cheekteeth-smaller.jpg , but without the ridges and colouring and facial features. Now, work along the line, having both lips touching the edge as well as the nose following the downwards slope, but not exactly along it.
I'm sorry if I don't make myself clear. DX